Presses universitaires de Franche-Comté
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Disponible - 628 SOR
Niveau 3 - Techniques
Sorption processes and pollution : conventional and non-conventional sorbents for pollutant removal from wastewaters
Résumé
Analyse du traitement des eaux usées, notamment dans l'industrie chimique. Aborde les principes et les propriétés du processus d'adsorption.
- Contributeur(s)
- Éditeur(s)
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Date
- DL 2010
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Notes
- Notes bibliogr.
- Bibliogr. Index
- En anglais
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Langues
- Français
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Description matérielle
- 1 vol. (489 p.) : ill. en noir et en coul., couv. ill. en coul. ; 26 cm
- Collections
- Sujet(s)
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ISBN
- 978-2-84867-304-2
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Indice
- 628 Techniques sanitaires et contrôle des déchets
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Quatrième de couverture
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This book shows a typical selection of the types of adsorbents studied and used in wastewater treatment, with emphasis on industrial effluents. The types of materials considered range from conventional sorbents such as carbons and silicas, to non-conventional solids such as sawdust and chitosan. Sorbents for specific applications (e.g. colour removal, metal extraction, fluoride removal) and new polymeric-based sorbents (calixarenes, molecularly imprinted polymers, cyclodextrins) are discussed in detail. For people who are new to the field, two special overview chapters, dealing with the principles and properties of adsorption processes, are provided at the beginning of the book. Also, the book provides a detailed review of sorption features.
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Tables des matières
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Sorption processes and pollution Conventional and non-conventional sorbents for pollutant removal from wastewaters
Grégorio Crini/Pierre-Marie Badot
Presses universitaires de Franche-Comté
- Preface 9
- List of contributors 11
- Abstracts 13
- Contents 17
- Chapter 1. Sorption processes and pollution: An introduction
- Grégorio Crini and Pierre-Marie Badot27
- Introduction 27
- Water pollution 28
- Different types of effluent28
- The variability of pollution28
- Wastewater treatment 30
- General scheme of wastewater treatment30
- Technologies available for pollutant removal31
- Sorption processes 34
- Activated carbon sorption34
- Non-conventional sorbent materials35
- Conclusions 36
- References 37
- Chapter 2. Wastewater treatment by sorption
- Grégorio Crini39
- Introduction 39
- Pollutants as sorbates 40
- Sorption processes 42
- Definitions42
- Batch methods44
- Sorbent materials45
- Characterization of sorbents46
- Types of sorbent material for pollutant removal49
- Control sorbent performance 55
- Influence of the solid characteristics55
- Surface chemistry of the sorbent55
- Activation conditions56
- Effect of operating variables56
- Effect of the solution conditions57
- Chemistry of the pollutant58
- Sorbent regeneration - desorption of pollutants58
- The mechanisms of sorption/adsorption/biosorption59
- Modeling61
- Freundlich and langmuir sorption isotherms63
- Error functions65
- Kinetics66
- Thermodynamic studies71
- Conclusions 72
- References 73
- Chapter 3. Fixed-bed adsorption studies
- Adriana S. Franca and Leandro S. Oliveira79
- Introduction 79
- Determination and prediction of breakthrough curves81
- Bohart and Adams model (BDST)84
- Clark model85
- Thomas model86
- Yoon and Nelson model87
- Wolborska model87
- Modified BDST model88
- Dose-response model89
- Constant pattern wave model90
- Mass transfer theory-based models91
- Applications in pollutant removal 94
- Concluding remarks 105
- Acknowledgements 106
- References 106
- Chapter 4. Adsorption of phenolic compounds on activated carbons
- Mariusz Barczak and Andrzej Dabrowski113
- Introduction 113
- Activated carbon as the basic adsorbent for uptake of phenols 117
- Precursors of activated carbons117
- Surface chemistry of activated carbon120
- Adsorption of phenols on activated carbon 121
- Role of the surface heterogeneity in the adsorption of phenols121
- Role of the porous structure on the adsorption of phenols124
- Irreversible adsorption of phenols 125
- Concluding remarks 127
- Acknowledgements 127
- References 127
- Chapter 5. Influence of thermal and chemical treatments on activated carbon characteristics, and effects on adsorption performance with respect to dyes, emerging contaminants and humic acids
- Sarra Gaspard, Marie-Julie Pintor, Axelle Durimel and Valérie Jeanne-Rose131
- Introduction 131
- Elaboration of activated charcoals 132
- Elaboration by physical activation134
- Chemical activation136
- Influence of activation method138
- Methods and tests for activated carbon characterization 139
- Usual methods140
- Original methods147
- Dyes adsorption 148
- Isotherm models148
- Dyes removal149
- Emerging contaminants and pesticides adsorption 154
- Humic substances157
- Concluding remarks 160
- Acknowledgments 160
- References 160
- Chapter 6. Silicas adsorbents for pollutants removal
- Slawomir Binkowski167
- Introduction 167
- Characteristics of silica 168
- Classification168
- Surface chemistry169
- Modification of the silica surface 171
- Modifying agents171
- Silane proadhesion compounds171
- Methods of modification172
- Adsorption of pollutants 175
- Types of pollutants175
- Adsorption of various pollutants on silica adsorbents176
- Conclusions 183
- Acknowledgments 184
- References 184
- Chapter 7. Non-conventional sorbents for dye removal
- François Renault, Nadia Morin-Crini, Pierre-Marie Badot and Grégorio Crini187
- General 187
- Dye molecules 188
- Langmuir equation 188
- Non-conventional sorbents for dye removal 189
- Activated carbons from solid wastes189
- Clays191
- Siliceous materials192
- Zeolites194
- Agricultural solid wastes194
- Industrial by-products196
- Peat197
- Chitin and chitosan198
- Biomass200
- Starch-based derivatives202
- Miscellaneous sorbents203
- Concluding remarks 204
- Acknowledgements 205
- References 205
- Chapter 8. Kaolin as an adsorbent for color removal
- Aparajita Goswami and Mihir Kumar Purkait215
- Introduction 215
- Techniques used for color removal from wastewater 217
- Physical techniques217
- Chemical techniques218
- Biological treatment218
- Different adsorbents used for treating colored water 218
- Kaolinite as an adsorbent for dye removal219
- Structure of kaolinite220
- Properties220
- How kaolinite adsorbed dye molecules221
- Modification of kaolin surface221
- Discussion 222
- Dye adsorption kinetics222
- Adsorption kinetic modeling and mechanism226
- Regeneration of adsorbent229
- Concluding remarks 230
- References 230
- Chapter 9. Wood sawdust, tree bark and wood chips: Waste lignocellulosic materials for dye removal
- Viorica Dulman and Simona-Maria Cucu-Man233
- Introduction 233
- Preparation and characterization of wood-derived lignocellulosic adsorbents 234
- Preparation of adsorbents234
- Characterization of adsorbents235
- Adsorption mechanism 238
- Factors affecting the batch adsorption of dyes on wood-derived lignocellulosic adsorbents 240
- Effect of pH240
- Effect of initial dye concentration and contact time243
- Effect of chemical treatment of adsorbent245
- Effect of particle size246
- Effect of adsorbent dose247
- Effect of salts and surfactants248
- Effect of agitation rate248
- Effect of temperature248
- Adsorption equilibrium 250
- Adsorption kinetic models 254
- Pseudo-first order model254
- Pseudo-second order model255
- Diffusion processes257
- Other kinetic models260
- Thermodynamic studies260
- Column studies 263
- Concluding remarks 266
- References 267
- Chapter 10. Polysaccharides for metal ion recovery - A focus on chitosan
- Jacques Desbrieres and Eric Guibal271
- Introduction 271
- Sorption mechanisms on chitosan 273
- Physico-chemistry of chitosan complexation273
- Electrostatic attraction and ion exchange mechanisms276
- Controlling parameters 278
- Crystallinity and swelling behavior278
- Diffusion properties279
- Metal speciation properties281
- Modes of application 284
- Chitosan in solution285
- Chitosan in batch/column285
- Specific conditionings286
- Example: application to recovery of metals from tannery waters in Morocco 287
- Chitosan and metal ions for the design of new materials 288
- Environmental applications288
- Analytical applications288
- Biological and biomedical applications289
- Catalytic applications290
- Biosensor and microdevices applications291
- Miscellaneous applications292
- Conclusions and perspectives 292
- References 293
- Chapter 11. Non-conventional adsorbents for the removal of metal compounds from wastewaters
- Fabio Montagnaro and Luciano Santoro297
- Introduction 297
- Use of non-conventional adsorbents: materials nature and properties, and beneficiation treatments 299
- Coal combustion ash and other industrial residues299
- Natural materials, agricultural by-products and other biomasses301
- Adsorption of metals on non-conventional adsorbents 302
- Specific adsorption capacity302
- Langmuir isotherm and thermodynamic parameters304
- Kinetic parameters305
- Controlling mechanisms308
- Concluding remarks 309
- Acknowledgements 310
- References 311
- Chapter 12. Pollutant removal from surface-treatment industry wastewaters by starch-based sorbents: Chemical abatement and impact on water toxicity
- Jérémie Charles, Bertrand Sancey, Giuseppe Trunfio, Pierre-Marie Badot, Michel De Carvalho, Albert Colin, Michaël Rietmann, Jean-François Minary, Emmanuel Grosjean and Grégorio Crini313
- Introduction 313
- Legislation for the control of discharge to the aquatic environment 314
- Pollution produced by surface-industries 316
- Different types of pollutants317
- The variability of pollution318
- Technologies available for pollutant removal from surface-finishing industry wastewater 320
- Chemical precipitation321
- Other methods323
- Separation, recovery and sorption processes 324
- Ion-exchange resins324
- Activated carbon adsorption324
- Adsorption using other materials325
- Biosorption of heavy metals326
- Starch-based materials327
- Chemical abatement and impact on water toxicity 327
- Closing comments 331
- Acknowledgements 331
- References 331
- Chapter 13. Defluoridation of water and wastewater using non-conventional sorbents
- Giuseppe Trunfio, Bertrand Sancey, Xavier Hutinet and Grégorio Crini335
- Defluoridation of water/wastewater 335
- Fluoride335
- Conventional treatments336
- Sorbents for fluoride removal 340
- Activated alumina and alumina-based sorbents340
- Carbon and carbon-based sorbents343
- Rare earth elements343
- Soils344
- Clays344
- Calcium346
- Zeolites346
- Hydroxide-based materials346
- Layered double hydroxides347
- Synthetic resins348
- Industrial by-products348
- Miscellaneous sorbents349
- Biopolymers349
- Chitosan and chitosan derivatives350
- Conclusion 352
- Acknowledgements 354
- References 354
- Chapter 14. Fungal biomasses: non conventional biosorbents for organic and inorganic pollutants
- Valeria Tigini, Valeria Prigione, Ilaria Donelli, Antonella Anastasi, Francesca Isella, Giuliano Freddi and Giovanna Cristina Varese359
- Introduction 359
- Biosorption as an important tool in water decontamination359
- Classification and characteristics of fungi361
- Fungal cell structure and composition with special reference to cell wall362
- Fungal biosorbents towards organic and inorganic pollutants 363
- Inorganic pollutants363
- Organic pollutants364
- Biotic parameters affecting fungal biosorption366
- Abiotic parameters affecting biosorption369
- Mechanisms and functional groups related to fungal biosorption374
- Analytical techniques useful in biosorption studies375
- Application of fungal biosorbents to real wastewaters378
- Future in fungal biosorbents381
- Acknowledgements 382
- References 382
- Chapter 15. Cross-linked cyclodextrins for pollutant removal
- Bertrand Sancey, Grégorio Crini, Giuseppe Trunfio, Nadia Morin-Crini and Giangiacomo Torri385
- General 385
- Synthesis of cross-linked cyclodextrin-based sorbents 387
- Materials modified by epichlorohydrin388
- Other materials prepared by direct cross-linking of cyclodextrin390
- Cross-linked cyclodextrins for pollutant removal 392
- A recent review of the literature392
- Sorption mechanism395
- Conclusions 396
- Acknowledgements 396
- References 397
- Chapter 16. Calixarene based materials for cations and anions
- Mustafa Yilmaz, Abdulkadir Sirit and Hasalettin Deligoz401
- Introduction 401
- Calixarene-based materials for cations 403
- Calixarene-based materials for alkali and alkaline earth metals404
- Calixarene-based materials for heavy metal ions 408
- Calixarene-based materials for toxic anions413
- Acknowledgements 416
- References 417
- Chapter 17. Recent advances in porosinit-based nanocomposite adsorbents for pollutants removal from waters
- Bingcai Pan, Xiaolin Zhang, Weiming Zhang, Lu Lv and Quanxing Zhang421
- Introduction 421
- Nano-metal/metallic compounds and their composite adsorbents 422
- Iron and iron (hydr)oxide423
- Carbonaceous nanomaterials and their composites 429
- Nano-polysaccharides and their composites 431
- Conclusion 432
- References 432
- Chapter 18. Molecularly imprinted polymers (mips) as selective sorbents for wastewater pollutants
- George Z. Kyzas and Nikolaos K. Lazaridis441
- Introduction 441
- Preparation of MIPs 443
- Selectivity444
- MIPs as sorbents for wastewater pollutants 445
- Dyes445
- Ions446
- Herbicides449
- Phenols451
- Pharmaceuticals/drugs452
- Conclusions and perspectives 453
- References 453
- Chapter 19. Nanoparticles for pollutants removal
- Yousef Haik and Shahnaz Qadri459
- Introduction 459
- Synthesis of nanoparticles 461
- Synthesis of carbon nanotubes461
- Synthesis of magnetic nanoparticles462
- Borohydride reduction463
- Chemical co-precipitation method463
- Refluxing in polyol method464
- Encapsulating the magnetic nanoparticles465
- Solvent displacement method465
- Salting out technique465
- Emulsion diffusion method466
- Solvent evaporation method466
- Polymer emulsion process466
- Magnetic separation467
- Adsorption models 468
- Sorption example 469
- Dye removal by use of magnetic nanoparticles469
- Preparation of magnetic nanoparticles469
- Characterization of magnetic nanoparticles470
- Dye solution471
- Equilibrium studies472
- Dye recovery474
- Dye removal by use of carbon nanotubes475
- Comparison between magnetic nanoparticles and carbon nanotubes477
- Nanotoxicity 477
- Concluding remarks 478
- References 478
- Biography and address of contributors 481
- Key-words 491
- Nomenclature 493
- Greek Letters 495
- Notation 495
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Origine de la notice:
- FR-751131015
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Disponible - 628 SOR
Niveau 3 - Techniques
