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CaO-SiO2-Al2O3-Fe Oxides Chemical System : Description and Applications
Livre CaO-SiO2-Al2O3-Fe Oxides Chemical System : Description and Applications

par Sorrentino, François

EDP Sciences

-

  • Disponible - 661 SOR

    Niveau 3 - Techniques

Livre

CaO-SiO2-Al2O3-Fe Oxides Chemical System : Description and Applications

Auteur(s) : Sorrentino, François Découvrir l'auteur

Résumé

Présentation du rôle des minéraux dans la construction de matériaux. La première partie décrit le processus tandis que la seconde est consacrée aux propriétés et à l'utilisation industrielle de certains minéraux.

  • Autre(s) auteur(s)
  • Éditeur(s)
  • Date
    • DL 2021
  • Langues
    • Anglais
  • Description matérielle
    • 1 vol. (337 p.) : couv. ill. en coul. ; 24 cm
  • Collections
  • Autre(s) édition(s)
  • Sujet(s)
  • ISBN
    • 978-2-7598-2480-9
  • Quatrième de couverture

    • CaO-SiO2-Al2O3-Fe Oxides Chemical System

      Description and Applications

      This book describes and comments on the results of research devoted to the studies of phase assemblages in the CaO-SiO2-Al2O3-Fe oxides chemical system, their stability and their evolution in our environment (temperature, pressure). Its aim is to be a research support, not only for researchers and development engineers but also more generally for others interested in materials sciences.

      The book is divided in two parts ; the first devoted to a description of « the system » using phase diagrams. The second explores the properties and uses of some of the minerals that are in widespread industrial and commercial use.

      Much of the work presented in this book is fully original and corresponds to the research undertaken by François Sorrentino from his time at the chemistry department of the University of Aberdeen during the early 1970's, to recent years when he has resumed his interest in mineral research, particularly related to the synthesis of calcium silicates and calcium aluminates, and their industrial manufacture.


  • Tables des matières

      • CaO-SiO2-Al2O3-Fe

      • Oxides Chemical System

      • Description and Applications

      • François Sorrentino, Denis Damidot and Charles Fentiman

      • Edp sciences

      • PrefaceIII
      • Part I - Descriptions
      • Chapter 1
      • One-Component Chemical Systems : CaO, SiO2, Al2O3 and Fe Oxides 3
      • 1.1 CaO3
      • 1.1.1 Introduction3
      • 1.1.2 Mineralogy, Structure and Stability3
      • 1.1.3 Properties and Applications4
      • 1.2 SiO25
      • 1.2.1 Introduction5
      • 1.2.2 Mineralogy5
      • 1.2.3 Structure and Stability6
      • 1.2.4 Properties and Applications6
      • 1.3 Al2O37
      • 1.3.1 Introduction7
      • 1.3.2 Mineralogy8
      • 1.3.3 Structure and Stability8
      • 1.3.4 Properties and Applications9
      • 1.4 Fe Oxides10
      • 1.4.1 Introduction10
      • 1.4.2 Mineralogy11
      • 1.4.3 Structure and Stability11
      • 1.4.4 Synthesis14
      • 1.4.5 Properties and Applications14
      • Chapter 2
      • Binary Chemical Systems 17
      • 2.1 CaO-SiO2 System17
      • 2.1.1 Introduction17
      • 2.1.2 Mineralogy17
      • 2.1.3 Structure, Polymorphism and Solid Solution18
      • 2.1.4 Stability and Phase Diagram of CaO-SiO2 System25
      • 2.1.5 Synthesis of Calcium Silicates27
      • 2.2 Al2O3-SiO2 System33
      • 2.2.1 Introduction33
      • 2.2.2 Mineralogy33
      • 2.2.3 Structure, Polymorphism and Solid Solutions33
      • 2.2.4 Stability and Phase Diagram37
      • 2.2.5 Synthesis of Alumino-Silicates41
      • 2.3 Al2O3-Fe Oxides System44
      • 2.3.1 Introduction44
      • 2.3.2 Mineralogy44
      • 2.3.3 Structure, Polymorphism and Solid Solution44
      • 2.3.4 Stability and Phase Diagram45
      • 2.3.5 Synthesis of Iron Aluminates48
      • 2.4 CaO-Al2O3 System48
      • 2.4.1 Introduction48
      • 2.4.2 Mineralogy49
      • 2.4.3 Structure, Polymorphism and Solid Solution49
      • 2.4.4 Stability and Phase Diagram55
      • 2.4.5 Synthesis of Calcium Aluminates57
      • 2.5 SiO2-Fe Oxides System62
      • 2.5.1 Introduction62
      • 2.5.2 Mineralogy62
      • 2.5.3 Structure, Polymorphism and Solid Solution63
      • 2.5.4 Liquid FeO-Fe2O3-SiO266
      • 2.5.5 Stability and Phase Diagram of the FeO-Fe2O3-SiO2 System67
      • 2.5.6 Synthesis of Iron Silicates71
      • 2.6 CaO-Fe Oxides System72
      • 2.6.1 Introduction72
      • 2.6.2 Mineralogy72
      • 2.6.3 Structure, Polymorphism and Solid-Solutions72
      • 2.6.4 Stability and Phase Diagram75
      • 2.6.5 Synthesis of Calcium Ferrite81
      • Chapter 3
      • Ternary Chemical Systems 83
      • 3.1 General Introduction83
      • 3.2 CaO-Al2O3-SiO2 System83
      • 3.2.1 Ternary Constituents of the CaO-Al2O3-SiO2 System83
      • 3.2.2 Mineralogy84
      • 3.2.3 Structure and Solid Solutions85
      • 3.2.4 Stability and Phases Diagrams (At One Atmosphere)90
      • 3.2.5 Compounds Obtained in Special Conditions97
      • 3.2.6 Stability Relative to Temperature or Pressure and Both98
      • 3.2.7 Thermodynamic Models99
      • 3.2.8 Synthesis of Calcium Silicoaluminate101
      • 3.3 Al2O3-SiO2-Fe Oxides103
      • 3.3.1 Introduction103
      • 3.3.2 Mineralogy103
      • 3.3.3 Structure and Solid Solution103
      • 3.3.4 Stability and Phase Diagram104
      • 3.3.5 Synthesis108
      • 3.4 CaO-SiO2-Fe Oxides109
      • 3.4.1 Introduction109
      • 3.4.2 Mineralogy109
      • 3.4.3 Structure and Solid Solution110
      • 3.4.4 Stability and Phase Diagrams in Air112
      • 3.4.5 Stablity and Phase Diagram in the CaO-SiO2-FeO System117
      • 3.4.6 CaO-SiO2-FeOx System at Various Oxygen Pressures126
      • 3.4.7 Model131
      • 3.4.8 Preparation and Synthesis132
      • 3.5 CaO-Al2O3-Fe Oxides134
      • 3.5.1 Introduction134
      • 3.5.2 Mineralogy134
      • 3.5.3 Structure and Solid Solutions135
      • 3.5.4 Stability and Phase Diagrams140
      • 3.5.5 Liquidus in Reducing Atmosphere143
      • 3.5.6 Model of the System145
      • 3.5.7 Formation and Synthesis145
      • Chapter 4
      • Quaternary Chemical Systems 147
      • 4.1 Introduction147
      • 4.1.1 Principle of Phase Equilibrium in a Quaternary System147
      • 4.2 CaO-SiO2-Al2O3-Fe2O3 System in Air152
      • 4.2.1 Quaternary Constituents of the CaO-SiO2-Al2O3-Fe Oxides System152
      • 4.2.2 Mineralogy153
      • 4.2.3 Mineralogy Structure Stability158
      • 4.2.4 Formation and Synthesis173
      • 4.3 CaO-Al2O3-SiO2-FeO System173
      • 4.3.1 Introduction173
      • 4.3.2 Ternary Systems Located Within the CaO, Al2O3, SiO2, FeO Tetrahedron173
      • 4.3.3 Binary Systems181
      • 4.3.4 Crystallized Solids182
      • 4.3.5 Univariant Lines and Quaternary Invariant Points182
      • 4.3.6 2CaO-SiO2-CaO SiO2-Gehlenite-FeO Quaternary System183
      • Chapter 5
      • Quinary Chemical Systems 189
      • 5.1 Introduction - Presentation of Quinary Data189
      • 5.2 CaO-SiO2-Al2O3-FeO-Fe2O3 System189
      • 5.2.1 Stability and Phase Diagrams189
      • 5.2.2 Conclusions192
      • References of Part I193
      • Part II - Applications
      • Chapter 6
      • Applications to Hydraulic Binders 211
      • 6.1 General Introduction211
      • 6.2 Portland Cements (PC)212
      • 6.2.1 Characteristics212
      • 6.2.2 PC Applications220
      • 6.2.3 Conclusions - Prediction of the Properties226
      • 6.3 Calcium Aluminate Cements (CAC)227
      • 6.3.1 CAC Characteristics227
      • 6.3.2 CAC Applications234
      • 6.4 Special Cements237
      • 6.4.1 Fast-Setting Cements237
      • 6.4.2 Geopolymers243
      • 6.4.3 Oil Well Gements246
      • 6.4.4 Expansive Cement251
      • 6.4.5 Dental Cements253
      • 6.4.6 Glass Cements259
      • Chapter 7
      • Application to Metal Refining 261
      • 7.1 General Introduction261
      • 7.2 Slags from Iron and Steel Industry261
      • 7.2.1 Blast Furnace Slags (BFS)261
      • 7.2.2 Converter Slags (Basic Oxygen Process or LD processing)266
      • 7.2.3 EAF Slags : High Carbon Steel269
      • 7.2.4 Ladle Slag (Secondary Metallurgy) - Stainless - High Alloy Steel Production269
      • 7.2.5 Refining Under Reducing Slag270
      • 7.3 Formation and Properties of Liquid Slags271
      • 7.4 Slags from Non Ferrous Industry272
      • 7.4.1 Copper Slag272
      • 7.4.2 Silico-Manganese Slag272
      • Chapter 8
      • Application to Refractory Materials 275
      • 8.1 Introduction275
      • 8.2 Raw Materials Based on Al2O3 and SiO2276
      • 8.2.1 Natural Raw Materials276
      • 8.2.2 Synthetic Raw Material277
      • 8.3 Applying Refractory Materials278
      • 8.3.1 Brick and Monolithic Refractories278
      • 8.3.2 Refractory Cement and Mortar281
      • 8.4 Refractories Consuming Industry286
      • 8.4.1 Iron and Steel Industry286
      • 8.4.2 Non-Ferrous Metal Industry287
      • 8.4.3 Cement Industry287
      • 8.4.4 Whiteware, Traditional Ceramic Industry288
      • 8.4.5 High-Tech Ceramic Industry288
      • 8.4.6 Glass Industry288
      • Chapter 9
      • Application of the Glassy Products 291
      • 9.1 Introduction291
      • 9.2 Structure of Glass292
      • 9.3 Classification of Glass Products Containing CaO, Al2O3, SiO2 and Fe Oxides293
      • 9.4 Products, Chemistry and Process294
      • 9.4.1 High Sihca Glass - Vycor Glass294
      • 9.4.2 Soda-Lime Glass295
      • 9.4.3 Sodium Borosilicate - Glass Fibres295
      • 9.4.4 Aluminosilicate Glass297
      • 9.4.5 Special Applications299
      • Chapter 10
      • Application of Ceramic Products 303
      • 10.1 Introduction to Ceramics303
      • 10.2 Structure of Ceramics303
      • 10.2.1 Processing of Manufacture303
      • 10.2.2 Shaping304
      • 10.2.3 Physico-Chemical Changes During Firing305
      • 10.3 Classification of Ceramic Products Containing CaO, SiO2, Al2O3 and Fe Oxides305
      • 10.3.1 Introduction305
      • 10.3.2 Traditional Ceramics305
      • 10.3.3 Ceramics in the Construction Sector Ceramics312
      • 10.3.4 High Technology Ceramics313
      • Chapter 11
      • Application as Fillers 315
      • 11.1 General Introduction315
      • 11.2 Mono-Component317
      • 11.2.1 Calcium Oxide317
      • 11.2.2 SiO2318
      • 11.2.3 Alumina319
      • 11.2.4 Fe oxides320
      • 11.3 Multi-Components By-Products from Industrial Process321
      • 11.3.1 Slags321
      • 11.3.2 Fly Ashes324
      • 11.3.3 Red Mud (KUR 1997)326
      • 11.3.4 Cement Kiln Dust (CKD)327
      • 11.4 Multi-Components from Natural Origin328
      • 11.4.1 Natural Pozzolans328
      • 11.4.2 Metakaolin330
      • 11.4.3 Rice Husk Ashes (RHA)331
      • 11.4.4 Wollastonite332
      • References of Part II335

  • Origine de la notice:
    • Abes ;
    • BPI

  • Disponible - 661 SOR

    Niveau 3 - Techniques